Description

The pH of a salt solution can be estimated based on knowledge of the dissociation constants and molarity.


NOTE: The following applies to a salt formed by a monoprotic acid and base.

 

Strength of a Acid or Base

Dissociation Constant (Kb)

weak

< 1

strong

>= 1

 

 

Acid

Base

 pH

strong

strong

7.0

strong

weak

0.5 * (pKw - pKb - LOG10(salt concentration))

weak

strong

0.5 * (pKw + pKa + LOG10(salt concentration))

weak

weak

0.5 * (pKw + pKa – pKb)

 

where:

• pKw = 14.00


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